Preheat: Preheat oven to 190°C (375°F). Line baking sheet with parchment.
Mix dry: In medium bowl, whisk together flour, cornstarch, dark cocoa powder, baking soda, baking powder, and salt.
Cream butter and sugars: Cut cold butter into cubes. Place in large bowl with brown sugar and granulated sugar. Beat until just combined, about 1 minute. Do not overmix.
Add eggs: Add whole egg and extra egg yolk. Mix until just combined.
Add dry ingredients: Add dry mix in two batches, mixing on low until no dry streaks remain. Do not overmix.
Fold chips: Add Reese's peanut butter baking chips. Fold gently with spatula until evenly distributed.
Portion: Divide dough into 4 equal portions of 170g each. Roll into balls. Do not flatten.
Bake: Place dough balls on prepared sheet, 10cm apart. Bake 15-17 minutes until edges set and centers still soft.
Cool: Let cookies rest on hot baking sheet for 10 minutes.
Transfer: Transfer to wire rack to cool completely.